How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning.
نویسندگان
چکیده
An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 26 شماره
صفحات -
تاریخ انتشار 2015